期刊
CHEMSUSCHEM
卷 12, 期 21, 页码 4838-4845出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201902079
关键词
amorphous materials; batteries; electrodes; hydrogen bonds; lithium
资金
- Taihu Electric Corporation [0001] Funding Source: Medline
An amorphous cross-linked binder is prepared from abundant and low-cost sodium alginate and carboxymethyl cellulose by protonation and mixing and is used to improve the electrochemical performance of silicon anodes in lithium-ion batteries. The amorphous cross-linked structure, formed by intermolecular hydrogen bonding between the functional groups in the two polymers, effectively enhances the flexibility and strength of the binder, resulting in strong adhesion between the binder and other components in the silicon anodes. Furthermore, the binder tolerates large volume changes and reduces the pulverization of silicon during the charge-discharge process. The hydrogen bonding in the binder helps to maintain the anode integrity during the volume change, leading to an excellent cycling stability and superior rate capability with a capacity of 1863mAhg(-1) at 500mAg(-1) after 150 cycles.
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