期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 14, 期 20, 页码 3502-3514出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201900843
关键词
gas separation; interfacial compatibility; metal-organic frameworks; mixed-matrix membranes
资金
- National Key Research and Development Program of China [2017YFF0205401]
- National Natural Science Foundation of China [21576017, 21436002, 31961133004]
- Higher Education and High-Quality and World-Class Universities [PY201613]
Traditional films cannot fully adapt to industrial applications and to intensified processes. Advanced mixed-matrix membranes comprising metal-organic frameworks (MOF) embedded in a polymer matrix have been developed with the goal of breaking the trade-off effect of traditional polymer membranes and achieving separation performance beyond Robeson's upper limit. The key challenges in the fabrication of MOF-based mixed-matrix membranes are an enhancement in compatibility between the inorganic filler and the polymer matrix, elimination of the irregular morphology and non-selective interfacial defects, and further improvement in the gas-separation performance. This review summarizes the recent advances in protocols and strategies in terms of designing interfacial interactions to enhance the MOF/polymer interface compatibility. This review aims at providing some meaningful insights into preparing MOF-based mixed-matrix membranes targeting ideal interfacial morphology and leading to excellent gas-separation performance.
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