期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 63, 页码 14290-14294出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903727
关键词
aldehyde deformylating oxygenase; aldehyde deformylation; Baeyer-Villiger reaction; nucleophilic reactivity; mu-peroxo-(FeFeIII)-Fe-III
资金
- Hungarian National Research Fund [OTKA K108489, GINOP-2.3.2-15-2016-00049]
The reactivity of the previously reported peroxo adduct [Fe-2(III)(mu-O-2)(MeBzim-Py)(4)(CH3CN)(2)](4+) (1) (MeBzim-Py=2-(2 '-pyridyl)-N-methylbenzimidazole) towards aldehyde substrates including phenylacetaldehyde (PAA), hydrocinnamaldehyde (HCA), propionaldehyde (PA), 2-phenylpropionaldehyde (PPA), cyclohexanecarboxaldehyde (CCA), and para-substituted benzaldehydes (benzoyl chlorides) has been investigated. Complex 1 proved to be a nucleophilic oxidant in aldehyde deformylation reaction. These models, including detailed kinetic and mechanistic studies, may serve as the first biomimics of aldehyde deformylating oxygenase (ADO) enzymes.
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