期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 59, 页码 13504-13508出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201903625
关键词
acrylic acid; carbon dioxide; NHC; nickel; nickelalactone
资金
- Japan Science and Technology Agency [JPMJCR12Y3] Funding Source: Medline
- Japan Society for the Promotion of Science [15H05800,17H06143] Funding Source: Medline
By using a nickel complex with an N-phosphinomethyl-N-heterocyclic carbene ligand (NHC-P), the reducing ability and thermal stability of the complex were improved considerably compared to the previously reported bipyridine and bisphosphine complexes, and acrylate salt was prepared from ethylene and CO2 with the highest TON ever reported for nickel systems even without using metallic zinc. Oxidative cyclization of ethylene and CO2 on the NHC-P nickel complex was found to proceed very rapidly compared to previous systems.
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