期刊
CHEMISTRY LETTERS
卷 48, 期 8, 页码 943-946出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190273
关键词
Near surface; Monomer viscosity; Reactive adhesive monolayer
资金
- Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT)
- KAKENHI [15H03860, 17K05740, 16J05484]
- Grants-in-Aid for Scientific Research [16J05484, 15H03860, 17K05740] Funding Source: KAKEN
We disclose that the viscosity of a polymerizable diacrylate monomer confined in a nano-gap between acryloyloxy-terminated monolayer surfaces exhibited exponential increase at a longer distance than that between methacryloyloxy-terminated surfaces owing to homology of chemical structure causing strong molecular interactions. These reactive monolayers showed the increase at significantly longer distances than silica surfaces modified with antisticking fluorinated chemisorbed monolayers used for UV nanoimprinting as well as unmodified silica surfaces.
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