期刊
CHEMISTRY LETTERS
卷 48, 期 9, 页码 1062-1064出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190338
关键词
Ru nanoparticles; Crystal structure control; Formation process
Face-centered cubic (fcc) Ru nanoparticles (NPs) have been recently synthesized by reducing Ru(III) acetylacetonate, despite bulk Ru having a hexagonal close-packed (hcp) structure. We observed the formation processes of fcc and hcp Ru NPs using X-ray diffraction and X-ray absorption fine structure. We concluded that the strong Ru-O bond between Ru and the acetylacetonate ligand leads to the formation of the fcc structure.
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