期刊
CHEMICAL ENGINEERING JOURNAL
卷 369, 期 -, 页码 57-63出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.03.080
关键词
Cyanometallic framework; Co3O4-NiO; Nanocomposite; Supercapacitors
资金
- National Natural Science Foundation [51672114]
- Natural Science Foundation of Jiangsu Province [BK20161357]
- Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology [HZ20180004]
The cyanometallic framework (CMF)-derived bimetallic oxide/graphene foam (GF) composites were synthesized by a solution immersion and subsequent annealing treatment. As a binder-free electrode for supercapacitors, the Co3O4-NiO/GF electrode exhibited remarkable electrochemical properties in terms of high specific capacity (766 F g(-1) at 1 A g(-1)), superior rate capability with 67% capacitance retention (0.5-10 A g(-1)), as well as excellent cycling stability (86% retention after 5000 cycles). The improved capacitance performances were ascribed to the strong synergistic interaction between hierarchical Co3O4-NiO and GF substrate, where metal oxides contributed to high pseudocapacitance and GF provided outstanding conductivity and structural stability of electrodes.
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