期刊
CHEMCATCHEM
卷 11, 期 21, 页码 5212-5226出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.201901246
关键词
chirality amplification; asymmetric catalysis; macromolecular helices; supramolecular helices; switchable catalysis
资金
- China Scholarship Council (CSC)
- French Agence Nationale de la Recherche [ANR-17-CE07-0002 AbsoluCat]
Connecting intrinsically achiral catalytic centers to helical polymers provides a new class of asymmetric catalysts whose selectivity exclusively stems from the chiral environment provided by the helical polymer. Chirality amplification phenomena allow to control the handedness and the helical sense excess of these polymers which in turn dictate the stereochemical direction and the extent of enantioinduction, respectively, obtained in the course of the asymmetric reaction. This minireview is focused on such helical catalysts built either on a covalent or a non-covalent scaffold and for which the handedness is controlled by an asymmetric polymerization reaction, by enantiopure monomers or by chiral additives. The selectivity of catalysts based on a dynamic helical backbone can be tuned by changing the solvent or with additives. The fact that the enantiomeric state of such asymmetric catalysts can be switched in a predictable way is particularly emphasized.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据