期刊
CELLULOSE
卷 26, 期 17, 页码 9335-9348出版社
SPRINGER
DOI: 10.1007/s10570-019-02707-3
关键词
Cotton fabrics; NH2-MIL-125(Ti); Metal organic frameworks; Superdrophobicity; Ultraviolet resistance; Durability
资金
- National Key Research and Development Program of China [2016YFA0101102]
- Educational Commission of Hubei Province [D20181701]
Superhydrophobic cotton fabrics with improved ultraviolet resistance were prepared via in situ growing NH2-MIL-125(Ti)(Ti-MOF) nanoparticles on cotton fibers and subsequently coating with polydimethylsiloxane (PDMS) under room temperature. The synergetic effect of Ti-MOFs nanoparticles and PDMS was critical and essential for obtaining a superhydrophobic coating with anti-UV property. The surface microstructure, chemical composition, and superhydrophobic property of the as-prepared fabrics were characterized by K/S value, scanning electron microscopy, X-ray photoelectron spectroscopy, energy dispersive spectroscopy, and water contact angle (WCA) measurements. The as-prepared cotton fabrics not merely exhibited desirable superhydrophobic property with a water contact angle (WCA) of 154.7 +/- 0.7 degrees and a sliding angle of 3.6 degrees, but also displayed the considerable UV resistance. The oil-water separation, stability of UV protection and superhydrophobicity were also investigated. The superhydrophobicity, anti-ultraviolet property, and K/S value of as-prepared PDMS/Ti-MOFs@cotton fabrics were stable after 300 cycles of abrasion and 5 cycles of washing. The facile synthesis technique provided a simple method for scalable construction of multifunctional fabrics. [GRAPHICS] .
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