期刊
CATALYSIS TODAY
卷 360, 期 -, 页码 99-105出版社
ELSEVIER
DOI: 10.1016/j.cattod.2019.08.011
关键词
Noble metals free photocatalyst; H-2; Composite material; ZnS; MoS2; Metal sulfide
资金
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- [285711]
- [2016-01-2482CONACyT]
- [20170208]
- [20180305]
- [20180198]
- [20195404]
- [20195270SIP]
ZnS/MoS2 composite material was prepared using a one-step solvothermal method, exhibiting excellent photocatalytic activity with high hydrogen yield under UV irradiation. The synergistic effect between ZnS and MoS2, as well as sulfur vacancies contributing to the enhancement of photocatalytic activity in the composite material, played a crucial role.
ZnS/MoS2 composite material was prepared by one-step solvothermal method at different molybdenum concentration. The structural properties of the composite material were analyzed by XRD, UV-vis DRS, TEM and XPS techniques, and the photocatalytic was evaluated for the hydrogen production under UV irradiation. The hydrogen yield reaches 606 mu mol h(-1) g(-1) for the material with 10% of molybdenum, which was 30 and 50% superior than that obtained using MoS2 and ZnS as photocatalyst, respectively. The increase in the photocatalytic activity may be associated to a synergistic effect produced by the interaction between ZnS and MoS2, as well as the formation of defects in the structure of ZnS, due to sulfur vacancies produced during the synthesis, which could be observed in the TEM analysis of the composite material.
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