期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 33, 期 11, 页码 -出版社
WILEY
DOI: 10.1002/aoc.5174
关键词
amides; aminocarbonylation; aryl halides; carbamoylsilanes; C-C coupling
资金
- Natural Science Youth Foundation [201701D221033]
- Natural Science Foundation
- Shanxi Province Foundation [2012011046-9, 0713]
A nickel-catalyzed aminocarbonylation of aryl halides using carbamoylsilane as an amide source leading to corresponding secondary or primary aromatic amides has been developed, in which the methoxymethyl and benzyl were used as amino protecting group. The protocol tolerates a broad range of aryl halides bearing different functional groups to afford good yields of aryl amides under mild reaction conditions. The types and the relative positions of substituents on the aryl ring make a notable impact on the coupling efficiency. The plausible mechanism of nickel-catalyzed aminocarbonylation has been suggested.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据