期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 19, 页码 4500-4505出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900803
关键词
Decarboxylation; Giese Additions; Photoactivation; Redox Active Ester; EDA complex
资金
- National Natural Science Foundation of China (NSFC) [21702039]
- Key Research and Development Program of Hainan Province [ZDYF2019155]
- Program for Innovative Research Team in University [IRT-16R19]
- China Postdoctoral Science Foundation [2018M640588]
We report herein a catalyst-free method to perform decarboxylative conjugated addition and hydrodecarboxylation of aliphatic N-(acyloxy)phthalimides (redox active esters, RAEs) through photoactivation of electron-donor-acceptor (EDA) complex with Hantzsch ester (HE) in N,N-dimethylacetamide (DMA) solution. The reactions present a green method to decarboxylatively construct carbon-carbon bond and to perform hydrodecarboxylation with broad substrate scope and functional group tolerance under mild blue light irradiation condition without recourse of popularly used photoredox catalysts.
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