期刊
ACS APPLIED MATERIALS & INTERFACES
卷 11, 期 35, 页码 31763-31776出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b04601
关键词
membranes; photocatalysis; photosensitizers; water treatment; solar energy
资金
- Helmholtz Association
A novel combination of a poly(vinylidene fluoride) (PVDF) membrane with pore size 0.2 mu m and a photosensitizer 5,10,15,20-tetrakis (pentafluorophenyl)-21H,23H-porphine palladium(II) (PdTFPP) makes a promising hybrid material for the generation of singlet oxygen (O-1(2)) and, thus, water treatment applications. The fabricated photocatalytic membrane exhibits permeability of 4280 +/- 250 L.m(-2).h(-1).bar(-1) and stable photocatalytic degradation performance over a 90 h period, when illuminated with green light (528 +/- 20 nm) and operated in a dead-end, single-pass configuration. Methylene blue (MB) degradation of 83% was achieved for MB concentration of 1 mg.L-1 under the flow rate of 0.1 x 10(-3) L.min(-1) (flux of 30 L.m(-2).h(-1)), light intensity of 21 mW.cm(-2), and PdTFPP loading of 25 mu mol.g(-1). Due to an enhanced mass transfer, the reaction rate of MB removal (with apparent rate constant of k(app) = 6.52 min(-1)) results in an efficient photodegradation of MB inside the PdTFPP-PVDF membrane. The influence of experimental parameters such as catalyst loading, flow rate, light intensity, and solute concentration on MB removal was investigated. This research enables the application of photocatalytic PdTFPP-PVDF membranes as a potential technology for water decontamination under visible-light illumination.
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