期刊
ACS APPLIED MATERIALS & INTERFACES
卷 11, 期 39, 页码 35827-35834出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.9b14464
关键词
bar coating; organic solar cells; ternary; non-fullerene; molecular ordering
资金
- National Natural Science Foundation of China [21774097]
- Natural Science Foundation of Hubei Province [2018CFAOSS]
An in situ spectroscopy ellipsometry technique is utilized to probe the molecular ordering sequences of PBDB-T2F/IT-4F/COi8DFIC ternary photovoltaic blends fabricated by bar-coating in air. The time-resolved dynamics show that the primary electron acceptor IT-4F aggregates ahead of the secondary acceptor COi8DFIC in the bar-coated photoactive layer, although the latter has much stronger crystallization ability. Wetting coefficient analysis supports that COi8DFIC locates at the interface between the host components PBDB-T-2F and IT-4F. We demonstrate that the suitable degree of phase separation with the presence of 20 wt % COi8DFIC facilitates exciton dissociation and charge transfer, leading to a remarkable power conversion efficiency of 13.2% as well as excellent stability of ternary organic solar cells (OSCs), which is among the highest reported efficiency for OSCs that were fabricated by scalable solution-casting in ambient conditions.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据