期刊
TOPICS IN CURRENT CHEMISTRY
卷 377, 期 4, 页码 -出版社
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s41061-019-0246-3
关键词
Fused heteroaromatic rings; Cross-dehydrogenative coupling; C-H activation; Intramolecular oxidative cyclization; Lewis acids; Metal-mediated
资金
- Facultad de Farmacia (Universidad Central de Venezuela)
The present review highlights the most important recent contributions toward the synthesis of functionalized fused heteroaromatic rings via intramolecular C-H activation mediated or catalyzed by transition metals. This type of reaction constitutes a versatile strategy to obtain a great variety of fused heterocyclic systems through the formation of carbon-carbon (C-C) and C-heteroatom bonds from direct coupling between two adjacent C-H bonds or C-H/H-X bonds. The revision is focused on the synthesis of fused heterocycles through two chemical processes: (1) metal-catalyzed intramolecular oxidative C-H activation, and (2) intramolecular C-H activation mediated by metallic Lewis acids.
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