4.7 Article

A Facile Method to Synthesize CdSe-Reduced Graphene Oxide Composite with Good Dispersion and High Nonlinear Optical Properties

期刊

NANOMATERIALS
卷 9, 期 7, 页码 -

出版社

MDPI
DOI: 10.3390/nano9070957

关键词

CdSe; RGO nanocomposites; carboxyl groups; third-order nonlinear optical property; Z-scan technique; good dispersion

资金

  1. National Natural Science Foundation of China [61875053, 61404045, U1404624]
  2. Scientific Research Funds of Henan University [CX0000A40680]

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CdSe-reduced graphene oxide (CdSe/RGO) composites were synthesized by a hydrothermal method. CdSe/RGO composites with different mass ratios were prepared. The structure and morphology of CdSe/RGO composites were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The synthesis of CdSe/RGO complexes was successfully demonstrated by Fourier infrared (FT-IR) and Raman spectra. CdSe nanoparticles in the CdSe/RGO composite were uniformly dispersed on the graphene surface. The study found that oxygen-containing functional groups such as hydroxyl (-OH) and carboxyl (-COOH) groups in graphene played a decisive role in the dispersion of CdSe. The third-order nonlinear optical properties of CdSe/RGO composites were measured by a single beam Z-scan technique. The experimental results showed that composites exhibited two-photon absorption and self-focusing nonlinear refraction properties. Additionally, the third-order nonlinear susceptibility of the composite material was obviously enhanced, which was mainly due to the good dispersion of CdSe nanoparticles on graphene.

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