期刊
CHEMELECTROCHEM
卷 6, 期 14, 页码 3621-3626出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/celc.201900704
关键词
glucose; biofuel cell; ruthenium complex; carbon nanotubes; pyrene
资金
- Labex ARCANE [ANR-11-LABX-0003-01]
- Graduate School on Chemistry, Biology and Health of Univ Grenoble Alpes CBH-EUR-GS [ANR-17-EURE-0003]
- Centre of Excellence of Multifunctional Architectured Materials CEMAM - Investments for the Future Program [AN-10-LABX-44-01]
A novel water-soluble Ru complex bearing phenanthrolinequinone ligands, diethyleneglycol linkers and pyrene anchoring groups was synthesized. Electrical wiring of NAD- and FAD-dehydrogenases is demonstrated via NADH oxidation and mediated electron transfer respectively. Bioelectrocatalysis is facilitated by the flexible and hydrophilic diethyleneglycol groups, and strong binding of pyrene groups with the carbon nanotubes (CNTs) of the electrodes. Furthermore, owing to the surfactant properties of the PEG-modified complex, high quality CNT dispersions were obtained for homogeneous buckypaper preparation.
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