期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 7, 期 15, 页码 13491-13496出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b03118
关键词
Metal-free; Additive-free; Regioselective cyclization; 1,6-Enynes; Acyl radicals
资金
- National Natural Science Foundation of China [21801142]
- Natural Science Foundation of Zhejiang Province [LQ18B020002]
- Ningbo Municipal Natural Science Foundation [2018A610242]
- K. C. Wong Magna Fund in Ningbo University
- Education Foundation of Zhejiang Province [Y201839260]
A regioselective cyclization of 1,6-enynes is reported by a tert-butyl hydroperoxide (TBHP)-mediated, one-pot, cascade reaction with commercially available carbonyl compounds under metal- and additive-free conditions. The reaction scope includes both 1,6-enynes and carbonyl compounds. A possible cascade reaction mechanism, consisting of acyl radical addition, intramolecular cyclization, and hydrogen abstraction, is proposed.
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