期刊
JOURNAL OF SAUDI CHEMICAL SOCIETY
卷 23, 期 8, 页码 1102-1108出版社
ELSEVIER
DOI: 10.1016/j.jscs.2018.10.007
关键词
Copper-catalyzed; Esterification; Sunnyl hydrazide; Alcohol; Sulfinic ester
资金
- National Natural Science Foundation of China [21563025]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_15R46]
- Yangtze River Scholar Research Project of Shihezi University [CJXZ201601]
The efficient Cu-catalyzed esterification of sulfonyl hydrazides with alcohols in air is described, providing sulfinic esters in good yields and broad scope. Mechanistic studies suggest that the reaction likely proceeds through free-radical formation including arylthio radical and arylsulfonyl radical, while arylsulfuric acid are the major esterification intermediate in this transformation. (C) 2019 King Saud University. Production and hosting by Elsevier B.V.
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