期刊
ACS MACRO LETTERS
卷 8, 期 8, 页码 996-1001出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.9b00355
关键词
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资金
- National Science Centre [DEC-2018/29/B/ST3/00889]
- Region Rhone-Alpes Auvergne
In this paper, we examine the transport properties of a 1,2,3-triazoliumbased poly(ionic liquid) (PIL) at ambient and elevated pressure up to 475 MPa. We show that the isothermal and isobaric conductivity measurements analyzed in the 3D plane give a unique possibility to estimate the thermodynamic (isothermal compressibility and thermal expansion coefficient) properties for PILs having a charge transport fully controlled by viscosity. This result, providing a direct connection between thermodynamic and dynamic properties of PILs, is of significant importance for both material scientists and practical applications.
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