期刊
SCIENTIFIC REPORTS
卷 9, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41598-019-41939-y
关键词
-
资金
- Australian Research Council's Industry Transformation Linkage Projects [IH 150100003]
- University of Adelaide
Supercapacitors (SCs) due to their high energy density, fast charge storage and energy transfer, long charge discharge curves and low costs are very attractive for designing new generation of energy storage devices. In this work we present a simple and scalable synthetic approach to engineer ternary composite as electrode material based on combination of graphene with doped metal oxides (iron oxide) and conductive polymer (polypyrrole) with aims to achieve supercapacitors with very high gravimetric and areal capacitances. In the first step a binary composite with graphene mixed with doped iron oxide (rGO/MeFe2O4) (Me = Mn, Ni) was synthesized using new single step process with NaOH acting as a coprecipitation and GO reducing agent. This rGO/MnFe2O4 composite electrode showed gravimetric capacitance of 147 Fg(-1) and areal capacitance of 232 mFcm(-2) at scan rate of 5 mVs(-1). In the final step a conductive polypyrrole was included to prepare a ternary composite graphene/metal doped iron oxide/ polypyrrole (rGO/MnFe2O4/Ppy) electrode. Ternary composite electrode showed significantly improved gravimetric capacitance and areal capacitance of 232 Fg(-1) and 395 mFcm(-2) respectively indicating synergistic impact of Ppy additives. The method is promising to fabricate advanced electrode materials for high performing supercapacitors combining graphene, doped iron oxide and conductive polymers.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据