Porous ionic liquid polymer: A reusable adsorbent with broad operating pH range for speciation of nitrate and nitrite

Ionic liquids (ILs) are a class of fluids with unique physicochemical properties employing polymeric substances emerging new materials. Solidification of ILs into porous materials generates porous ionic liquid polymers that combine the unique characteristics of ILs with common porous materials and polymers. In this study, it's the first time the porous ionic liquid polymer was chosen as a sorbent for extraction and speciation of nitrite and nitrate. Porous IL was prepared through polymerization of 1-allyl-3-methylimidazolium bromide monomers in the presence of azobisisobutyronitrile (AIBN) and crosslinking of ethylene glycol dimethyl acrylate (EGDMA). Parameters affecting the adsorbent performance were optimized. Under the optimal conditions, correlation coefficient (R-2) was 0.9996 and LOD was 0.1 mu g L-1. This method presented the linearity in the concentration range between 0.1-100 mu g L-1 and the relative standard deviation was 3.2%. Finally, the adsorption behavior of the obtained sorbent for nitrate and nitrite determination in various real samples was evaluated. The result indicates that the porous ionic liquid polymer showed high adsorption capacity (233 mg g(-1)). The convenient preparation of the porous ionic liquid material, as well as high adsorption capacity for anionic pollutants predicted its broad application potential in anion removal materials.