期刊
ADVANCED ENERGY MATERIALS
卷 9, 期 37, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201901667
关键词
catalysis; charge field; lithium-sulfur batteries; sulfur cathodes; yolk-shell
类别
资金
- Ministry of Science and Technology of China [2018YFA0209102]
- National Natural Science Foundation of China [51601040, 11727807, 51725101, 51672050, 61790581, 51672049, 51871060]
- Science and Technology Commission of Shanghai Municipality [16DZ2260600]
- China Postdoctoral Science Foundation [2018M640337]
Inhibiting the shuttle effect of lithium polysulfides and accelerating their conversion kinetics are crucial for the development of high-performance lithium-sulfur (Li-S) batteries. Herein, a modified template method is proposed to synthesize the robust yolk-shell sulfur host that is constructed by enveloping dispersive Fe2O3 nanoparticles within Mn3O4 nanosheet-grafted hollow N-doped porous carbon capsules (Fe2O3@N-PC/Mn3O4-S). When applied as a cathode for Li-S batteries, the as-prepared Fe2O3@N-PC/Mn3O4-S can deliver capacities as high as 1122 mAh g(-1) after 200 cycles at 0.5 C and 639 mAh g(-1) after 1500 cycles at 10 C, respectively. Remarkably, even as the areal sulfur loading is increased to 5.1 mg cm(-2), the cathode can still maintain a high areal specific capacity of 5.08 mAh cm(-2) with a fading rate of only 0.076% per cycle over 100 cycles at 0.1 C. By a further combination analysis of electron holography and electron energy loss spectroscopy, the outstanding performance is revealed to be mainly traced to the oxygen-vacancy-induced interfacial charge field, which immobilizes and catalyzes the conversion of lithium polysulfides, assuring low polarization, fleet redox reaction kinetics, and sufficient utilization of sulfur. These new findings may shed light on the dependence of electrochemical performance on the heterostructure of sulfur hosts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据