期刊
ACS CATALYSIS
卷 9, 期 8, 页码 6751-6754出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b01785
关键词
nickel; electrochemistry; enantioselective; cross-coupling; asymmetric catalysis
资金
- National Science Foundation (Graduate Research Fellowship) [DGE-1144469]
- NIH [R3SGM118191-01]
An electrochemically driven enantioselective nickel-catalyzed reductive cross-coupling of alkenyl bromides and benzyl chlorides is reported. The reaction forms products bearing allylic stereogenic centers with good enantioselectivity under mild conditions in an undivided cell. Electrochemical activation and turnover of the catalyst mitigate issues posed by metal powder reductants. This report demonstrates that enantioselective Ni-catalyzed cross-electrophile couplings can be driven electrochemically.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据