期刊
ACS CATALYSIS
卷 9, 期 7, 页码 6583-6587出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b02005
关键词
vinyl epoxides; borylation; copper catalysis; allylic alcohols; skipped dienes
资金
- European Research Council [ERC-337776]
- MINECO [CTQ2016-78779-R]
We present an efficient strategy for the formal 1,4-reduction of vinyl epoxides that does not require superstoichiometric amounts of a strong reductant. Using a readily available copper catalyst and a diboron compound, a wide variety of enantioenriched allylic alcohols have been prepared. Additionally, epoxyenynes have been reduced in a 1,4-manner to selectively afford skipped enynes or skipped dienes.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据