期刊
ACS CATALYSIS
卷 9, 期 8, 页码 6744-6750出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b01911
关键词
copper; 1,3-dienes; borylation; asymmetric catalysis; cyanation
资金
- EPSRC [EP/MOOS062/1]
- Royal Society (Newton International Fellowship)
- University of Manchester
- EPSRC [EP/P001386/1] Funding Source: UKRI
A multicomponent copper-catalyzed enantio- and regioselective borocyanation of 1-aryl-1,3-butadienes has been developed. The method provides access to functionalized allylic nitriles in up to 90% yield and 94% ee and thus overcomes some of the long-standing problems associated with the enantioselective insertion of cyano groups into unsaturated organic molecules. Both boron and cyano functionalities can be used as handles for selective manipulation.
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