期刊
NATURE COMMUNICATIONS
卷 10, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41467-019-10519-z
关键词
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资金
- European Union's Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant [747422]
- Netherlands Organisation for Scientific Research [016.Veni.192.106]
- Chinese Academy of Sciences [XDB12020200]
- King Abdullah University of Science and Technology (KAUST)
- European Community's Seventh Framework Programme (FP7/2007-2013) [607585]
- European Research Council (ERC Grant) [33903]
- Ministry of Education, Culture, and Science (Gravity program) [024.001.035]
- Foundation for Polish Science - European Union under the European Regional Development Fund [First TEAM/2017-3/26]
- Marie Curie Actions (MSCA) [747422] Funding Source: Marie Curie Actions (MSCA)
Polymorphism of organic semiconducting materials exerts critical effects on their physical properties such as optical absorption, emission and electrical conductivity, and provides an excellent platform for investigating structure-property relations. It is, however, challenging to efficiently tune the polymorphism of conjugated polymers in aggregated, semi-crystalline phases due to their conformational freedom and anisotropic nature. Here, two distinctly different semi-crystalline polymorphs (beta(1) and beta(2)) of a low-bandgap diketopyrrolopyrrole polymer are formed through controlling the solvent quality, as evidenced by spectroscopic, structural, thermal and charge transport studies. Compared to beta(1), the beta(2) polymorph exhibits a lower optical band gap, an enhanced photoluminescence, a reduced pi-stacking distance, a higher hole mobility in field-effect transistors and improved photocurrent generation in polymer solar cells. The beta(1) and beta(2) polymorphs provide insights into the control of polymer self-organization for plastic electronics and hold potential for developing programmable ink formulations for next-generation electronic devices.
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