期刊
NATURE COMMUNICATIONS
卷 10, 期 -, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41467-019-10289-8
关键词
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资金
- Center for Advanced Soft-Electronics - Ministry of Science, ICT and Future Planning as Global Frontier Project [CASE-2015M3A6A5072945]
- NRF [2017R1A4A1015323, 2017R1D1A1B03028004]
- Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy under the Advanced Battery Materials Research (BMR) program [DE-AC02-05CH11231, 18769, 6951379]
- DOE's Office of Biological and Environmental Research
- Department of Energy [DE-AC05-76RLO1830]
- National Research Foundation of Korea [2017R1D1A1B03028004, 2017R1A4A1015323] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A fast-charging battery that supplies maximum energy is a key element for vehicle electrification. High-capacity silicon anodes offer a viable alternative to carbonaceous materials, but they are vulnerable to fracture due to large volumetric changes during charge-discharge cycles. The low ionic and electronic transport across the silicon particles limits the charging rate of batteries. Here, as a three-in-one solution for the above issues, we show that small amounts of sulfur doping (< 1 at%) render quasi-metallic silicon microparticles by substitutional doping and increase lithium ion conductivity through the flexible and robust selfsupporting channels as demonstrated by microscopy observation and theoretical calculations. Such unusual doping characters are enabled by the simultaneous bottom-up assembly of dopants and silicon at the seed level in molten salts medium. This sulfur-doped silicon anode shows highly stable battery cycling at a fast-charging rate with a high energy density beyond those of a commercial standard anode.
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