期刊
ULTRASONICS SONOCHEMISTRY
卷 58, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.ultsonch.2019.104705
关键词
Nitrogen-aeration; Ultrasonic synthesis; SiO2@PNIPAm; Temperature responsive Pickering emulsion
资金
- Natural science Foundation of China [51327901, 51727803, 51571164]
- Natural Science Foundation of Shaanxi Province [2016JM2023, 2019KW-024]
Ultrasonic synthesis has shown great potential applications in preparing varieties of nanostructured materials. However, fabrication of nanomaterials with tunable structures and desirable properties is still challenging because of the instability and nonuniform distribution of cavitation effect in liquid phase. In this study, a novel aeration tuned ultrasonic synthesis approach is proposed for optimizing the cavitation effect in both time and space scales and fabricating SiO2@PNIPAm NPs. By alternation of ultrasonication and N-2 aeration, more and more gas bubbles are formed in the reaction liquid, and the collapse of those bubbles is further enhanced by the reactants of solid SiO2 and intermediate functionalized SiO2 NPs. As a result, SiO2@PNIPAm NPs with various grafting ratios are successfully synthesized simply by changing the number of ultrasonic synthesis cycle. The SiO2@PNIPAm NPs are subsequently used as stabilizer to form Pickering emulsions with different temperature response. This work provides a potential facile sonochemical synthesis method with high efficiency in obtaining inorganic/organic NPs of well determined structures.
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