期刊
TETRAHEDRON
卷 75, 期 24, 页码 3265-3271出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2019.04.028
关键词
Cycloaddition; Enantioselective; Lewis-acid; Allenes; Cyclobutane
资金
- Indiana University
- National Institutes of Health [R01GM110131]
- Deutsche Forschungsgemeinschaft [WI 4933/1-2]
- Vice Provost for Research through the Research Equipment Fund
- NSF [CHE1726633]
The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported. In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the allenic esters generally used in these cycloadditions. (C) 2019 Elsevier Ltd. All rights reserved.
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