期刊
SYNTHESIS-STUTTGART
卷 51, 期 18, 页码 3511-3519出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611888
关键词
styrenes; metal free; dicarbonyl indoles; synthetic methods
资金
- National Key Research and Development Program of China [2016YFB0301501]
- National Natural Science Foundation of China [21776130, 21878145]
- Jiangsu Synergetic Innovation Center for Advanced Bio-Manufacture [X1821, X1802]
- Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP)
- Postgraduate Research & Practice Innovation Program of Jiangsu Province
A new and efficient method for the synthesis of C-3 dicarbonyl indoles via oxidative cross-coupling of styrenes with indoles under metal-free conditions has been developed. Moreover, a broad scope of C-3 dicarbonyl indoles in moderate to good yields were obtained, and a plausible mechanism is proposed based on control and isotope-labeling experiments.
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