期刊
SYNLETT
卷 30, 期 17, 页码 1954-1965出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1689924
关键词
carbonyl-olefin metathesis; hydrazines; 1,3-dipolar cycloadditions; azomethine imines; cycloreversion
资金
- National Science Foundation [CHE-0953259]
Carbonyl-olefin metathesis is a potentially powerful yet underexplored reaction in organic synthesis. In recent years, however, this situation has begun to change, most notably with the introduction of several different catalytic technologies. The development of one of those new strategies, based on hydrazine catalysts and a novel [3+2] paradigm for double bond metathesis, is discussed herein. First, the stage is set with a description of some potential applications of carbonyl-olefin metathesis and a discussion of alternative strategies for this intriguing reaction.
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