期刊
SMALL
卷 15, 期 36, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201902466
关键词
arrays; hybrid; Na-3(VO)(2)(PO4)(2)F; quasi-solid-state; sodium-ion capacitors
类别
资金
- National Natural Science Foundation of China (NSFC) [51702295]
Sodium-vanadium fluorophosphate (Na3V2O2x(PO4)(2)F3-2x, NVPF, 0 <= x <= 1) is considered to be a promising Na-storage cathode material due to its high operation potentials (3.6-4 V) and minor volume variation (1.8%) during Na+-intercalation. Research about NVPF is mainly focused on powder-type samples, while its ordered array architecture is rarely reported. In this work, large-area and uniform Na-3(VO)(2)(PO4)(2)F cuboid arrays are vertically grown on carbon nanofiber (CNF) substrates for the first time. Owing to faster electron/ion transport and larger electrolyte-electrode contact area, the as-prepared NVPF array electrode exhibits much improved Na-storage properties compared to its powder counterpart. Importantly, a quasi-solid-state sodium-ion hybrid capacitor (SIHC) is constructed based on the NVPF array as an intercalative battery cathode and porous CNF as a capacitive supercapacitor anode together with the P(VDF-HFP)-based polymer electrolyte. This novel hybrid system delivers an attractive energy density of approximate to 227 W h kg(-1) (based on total mass of two electrodes), and still remains as high as 107 Wh kg(-1) at a high specific power of 4936 W kg(-1), which pushes the energy output of sodium hybrid capacitors toward a new limit. In addition, the growth mechanism of NVPF arrays is investigated in detail.
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