Investigation on emission control of NOx precursors and phosphorus reclamation during pyrolysis of ferric sludge

In this study, a method to reduce the emission of NOx precursors (e.g., hydrogen cyanide (HCN) and ammonia (NH3)) while simultaneously reclaim more plant-available P was proposed through pyrolyzing ferric sludge (sludge conditioned by Fenton's reagents) rather than raw sludge. The nitrogen and phosphorus transformation at different pyrolysis temperatures was investigated. The results indicated that in comparison with the pyrolysis of raw sludge, the remaining iron compounds in ferric sludge can fix char-N in more stable forms (e.g., appearance of pyrrole-N at 900 degrees C). The secondary cracking of amine-N compounds in tar-N (e.g.. 81.67% increase of amine-N at 900 degrees C) can be inhibited. Hence, more amine-N was remained and less heterocyclic-N and nitrile-N compounds were generated in tar-N. Less generation of NH3-N and HCN-N was also observed in NOx precursors (e.g., 5.46% decrease of NH3 -N and 6.91% decrease of HCN-N at 900 degrees C). Moreover, the results of X-ray diffractometry, liquid(31) P nuclear magnetic resonance spectroscopic, X-ray photoelectron spectroscopic, and chemical analyses collectively indicated that iron present in ferric sludge also favored reclamation of more plant-available P. In comparison with the pyrolysis of raw sludge, an increase in the total phosphorus pool was noted (18.06-36.26 versus 15.54-30.59 mg g(-1) dry solids). A decrease in mobility with the predominant P as sodium hydroxide (NaOH)-P, and an increase in plant-available P can be also obtained. This study indicated that pyrolysis of ferric sludge was a feasible way to simultaneously reduce emission of NO(x )precursors, reclaim plant-available P, and reuse ferric sludge. (C) 2019 Elsevier B.V. All tights reserved.