期刊
ORGANIC LETTERS
卷 21, 期 15, 页码 5917-5921出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02055
关键词
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资金
- National Key Research and Development Program of China [2017YFA0402800]
- National Natural Science Foundation of China [51772285, 21473170]
Herein, we explore phenanthrene as the building block to synthesize a hoop-shaped [6,6]carbon nanotube segment from a planar macocycle via a Diels-Alder reaction. The phenanthrene-based coronal nanohoop 7 was fully characterized by HR-MS, NMR, and other spectroscopies. In addition, its photophysical properties and the supramolecular interactions between 7 and fullerene C-60 were investigated. This present work suggests an easily accessible Diels-Alder reaction strategy to synthesize cylindrical nanohoops.
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