期刊
ORGANIC LETTERS
卷 21, 期 13, 页码 4971-4975出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01456
关键词
-
资金
- National Natural Science Foundation of China [21402244]
A rhodium(III)-catalyzed one-pot three-component reaction of N-methoxybenzamide, alpha-diazoester, and alkyne was developed, providing an alternative way to synthesize isoquinoline derivatives. Mechanistically, it is a relay catalysis, and the reaction occurred via successive O-alkylation and C-H activation processes, both of which were promoted by the same catalyst.
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