期刊
ORGANIC LETTERS
卷 21, 期 13, 页码 5197-5200出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01801
关键词
-
资金
- National Natural Science Foundation of China [21772086]
- Natural Science Foundation of Jiangsu Province [BK20181254]
Disclosed is a mild, reliable, and enantioselective catalytic parallel kinetic resolution of unsymmetrical acyclic aliphatic syn-1,3-diol derived acetals mediated by chiral phosphoric acid. This method provides stereoselective access to a variety of syn-1,3-diols as valuable building blocks with high enantioselectivity. Moreover, this mild system allows for site-selective protection of optically pure syn-1,3-diols in excellent regioselectivity.
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