期刊
ORGANIC LETTERS
卷 21, 期 16, 页码 6337-6341出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02232
关键词
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资金
- Japanese Society for the Promotion of Science (JSPS)/the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan [25350960]
- Kurata Memorial Hitachi Science and Technology
- NOVARTIS Foundation (Japan) for the Promotion of Science
- Grants-in-Aid for Scientific Research [25350960] Funding Source: KAKEN
The heterocyclic portions of yuzurimine-type alkaloids, such as deoxyyuzurimine and macrodaphnine, were synthesized by using a stereoselective hydroboration-oxidation reaction to install the C20 methyl group, the intramolecular Mitsunobu reaction to construct the E-ring portion, and the intramolecular S(N)2 reaction to construct the F-ring portion as key steps.
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