期刊
ORGANIC LETTERS
卷 21, 期 14, 页码 5509-5513出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01829
关键词
-
资金
- National Natural Science Foundation of China
- Science and Technology Commission of Shanghai Municipality
- Education Commission of Shanghai Municipality
A highly chemo- and enantioselective hydrogenation of beta-diketones was achieved by using [Ru(benzene)(S)-SunPhosCl]Cl for consistency in THF. The neighboring heteroatoms played important roles in guaranteeing the reactivity and controlling the chemoselectivity. These results suggested a potential approach for the clean and facile synthesis of functionalized chiral beta-hydroxy ketones, which could otherwise be prepared through much less step-economic transformations.
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