期刊
ORGANIC LETTERS
卷 21, 期 14, 页码 5600-5605出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01908
关键词
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资金
- Natural Science Foundation of China [21502094, 21602200]
- Natural Science Foundation of the Jiangsu Higher Education Institutions of China [17KJA220003]
- advanced analysis and testing center of Nanjing Forestry University
- Doctorate Fellowship Foundation of Nanjing Forestry University
A metal-free method for formal beta-arylation/heteroarylation of ketones through efficient cyclopropanol ring-opening cross-couplings with aryl sulfoxides at room temperature has been developed. This protocol shows a broad substrate scope and promising scalability. In addition, the utility of the beta-arylated ketones is further demonstrated through a variety of postcoupling transformations and synthetic applications.
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