期刊
ORGANIC LETTERS
卷 21, 期 16, 页码 6185-6189出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01690
关键词
-
资金
- KAKENHI [JP16H01127, JP16H00999, JP26253001, JP18H02549, JP18H04231, JP18H04379, JP18K18462]
- Platform Project for Supporting Drug Discovery and Life Science Research (BINDS) from AMED [JP18am0101100]
An indole synthesis via ring expansion of benzocyclobutenone oxime sulfonate was developed. Utility of the indole synthesis was demonstrated by the total synthesis of (+)-CC-1065. The middle and right segments were constructed by a sequential ring expansion of the symmetrical benzo-bis-cyclobutenone. The left segment was also constructed via ring expansion of the methyl-substituted benzocyclobutenone oxime sulfonates. After condensation of these three segments, the dienone cyclopropane structure was formed to complete the total synthesis.
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