期刊
ORGANIC LETTERS
卷 21, 期 16, 页码 6413-6417出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b02269
关键词
-
资金
- National Science Foundation of China [21672066]
The classic transformations of N-sulfonyl-1,2,3-trazoles were processed via nitrogen anion (hydrolysis, etc.) and carbene intermediates, and no efficient examples via radical intermediates were developed. Here, we reported a catalyst-free radical chain transformation of N-sulfonyl-1,2,3-triazoles to access an intermolecular oxidative C(sp(3))-H coupling to yield N-2-selective products in air without any catalysts.
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