期刊
ORGANIC LETTERS
卷 21, 期 12, 页码 4721-4724出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.9b01593
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资金
- JSPS KAKENHI [JP19H02726, JP18H04272, JP15H05799, JP19K15573]
A Pd-catalyzed intramolecular C-H arylation of nitroarenes has been developed. Nitroarenes bearing tethered aryl groups at the ortho-position can be readily prepared in one step from 2-halonitroarenes by a nucleophilic aromatic substitution (SNAr). Under Pd/BrettPhos catalysis, activations of the C-NO2 bond as well as the C-H bond on arenes generated the corresponding biaryl linkage in moderate to excellent yields.
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