期刊
APPLIED SURFACE SCIENCE
卷 389, 期 -, 页码 311-315出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2016.06.193
关键词
Ceria; Particle size; Oxidation state; Adsorption isotherm; Silicate ions
类别
资金
- Technology Innovation Program - Ministry of Trade, industry & Energy (MI, Korea) [201500000001419]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10044666] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this study, we have investigated the role of the Ce oxidation state (Ce3+/Ce4+) on the CeO2 surfaces for silicate adsorption. In aqueous medium, the Ce3+ sites lead to the formation of -OH groups at the CeO2 surface through H2O dissociation. Silicate ions can adsorb onto the CeO2 surface through interaction with the -OH groups (-Ce-OH- + -Si-O- <-> -Ce-O-Si- + OH-). As the Ce3+ concentration increased from 19.3 to 27.6%, the surface density of -OH group increased from 0.34 to 0.72 OH/nm(2). To evaluate the adsorption behaviors of silicate ions onto CeO2 NPs, we carried out an adsorption isothermal analysis, and the adsorption isotherm data followed the Freundlich model. The Freundlich constant for the relative adsorption capacity (K-F) and adsorption intensity (1/n) indicated that CeO2 NPs with high Ce3+ concentration show higher adsorption affinity with silicate ions. As a result, we have demonstrated that the Ce oxidation state (Ce3+/Ce4+) on the CeO2 surface can have a significant influence on the silicate adsorption. (C) 2016 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据