期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 25, 页码 9819-9822出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b04665
关键词
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资金
- Sasakawa Scientific Research Grant from The Japan Science Society [2019-3002]
- JSPS [17H05430]
- JSPS KAKENHI [17H06173]
- Nagase Science and Technology Foundation
- Sumitomo Foundation
- HOKUSAI GreatWave and BigWaterfall (RIKEN) [G18008]
We present the first quadruple borylation reaction of terminal alkynes, affording functionalized 1,1,2,2-tetrakis(boronate) derivatives in a chemo-/regioselective manner. The methodology is operationally simple and a novel B-B bond activation without the need for a transition-metal catalyst.
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