期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 29, 页码 11353-11357出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b03217
关键词
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资金
- National Nature Science Foundation of China [21872109]
- China Postdoctoral Science Foundation [2018M640994, 2018T111034]
- Cyrus Tang Foundation
- Fundamental Research Funds for the Central Universities [xjj2018033]
Effective activation of CO2 is a prerequisite for efficient utilization of CO2 in organic synthesis. Precisely controlling the interfacial events of solids shows potential for activation. Herein, defect-enriched CO2 with constructed interfacial frustrated Lewis pairs (FLPs, two adjacent Ce3+center dot center dot center dot O2-) effectively activates CO2 via the interactions between C/Lewis basic lattice O2- and the two O atoms in CO2/two adjacent Lewis acidic CO2 ions. Selective cyclic carbonate production from a catalytically tandem protocol of olefins and CO2 is used to demonstrate FLP-inspired CO2 activation.
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