期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 29, 页码 11425-11429出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b05961
关键词
-
资金
- National Research Foundation of South Africa
- Stellenbosch University
- SASOL
Either of two different isomeric products can be selectively obtained by photochemical [2+2] cycloaddition of 1,4-bis[2-(4-pyridyl)ethenyl]-benzene within a porous coordination polymer (PCP). The cycloaddition product obtained depends on the temperature at which irradiation occurs. A rare temperature induced phase transition alters the conformation of the photoactive ligand in the PCP, and thereby the positions at which cycloaddition occurs. We show that the multistimulus responsive nature of this particular PCP is due to the flexibility of the ligands employed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据