期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 141, 期 30, 页码 11775-11780出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b04619
关键词
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资金
- National Natural Science Foundation of China [201877043, 21702068, 21672077, 21761132014]
- Wuhan Creative Talent Development Fund
- Fundamental Research Funds for the Central Universities [2017KFYXJJ150]
Herein, we reported on a highly efficient glycosylation reaction comprising two chronological meticulously designed catalytic cycles: (1) rhodium-catalyzed formation of sulfonium ylide and (2) Bronsted acid-catalyzed formation of sulfonium ion. This protocol highlighted an effective and robust tactic to prepare a glycosyl sulfonium ion from a glycosyl sulfonium ylide precursor amenable for glycosylation.
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