期刊
APPLIED SURFACE SCIENCE
卷 362, 期 -, 页码 210-216出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2015.11.254
关键词
PECVD; Plasma polymerization; Thin film; Super-hydrophobic; Contact angle
类别
资金
- Scientific and Technological Research Council of Turkey (TUBITAK) [213M399]
Thin films of poly(2,2,3,4,4,4 hexafluorobutyl acrylate-glycidyl methacrylate) (P(HFBA-GMA) were deposited on different surfaces using an inductively coupled RF plasma reactor. Fluorinated polymer was used to impart hydrophobicity, whereas epoxy polymer was used for improved durability. The deposition at a low plasma power and temperature was suitable for the functionalization of fragile surfaces such as textile fabrics. The coated rough textile surfaces were found to be superhydrophobic with water contact angles greater than 150 due to the high retention of long fluorinated side chains. The hydrophobicity of the surfaces was observed to be stable after many exposures to ultrasonification tests, which is attributed to the mechanical durability of the films due to their epoxide functionality. FTIR and XPS analyses of the deposited films confirmed that the epoxide functionality of the polymers increased with increasing glycidyl methacrylate fraction in the reactor inlet. The modulus and hardness values of the films also increase with increasing epoxide functionality. (C) 2015 Elsevier B.V. All rights reserved.
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