期刊
JOURNAL OF POWER SOURCES
卷 429, 期 -, 页码 75-79出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2019.04.117
关键词
Solid electrolyte; Perovskite; Spark plasma sintering; All-solid-state battery; Lithium-sulfur battery
资金
- National Natural Science Foundation of China [51572145, 51872159, 51874151]
A solid Li+ electrolyte, which has a high Li+ conductivity at 25 degrees C and a high density, is required in rechargeable Li-ion batteries including all-solid-state Li-metal batteries and Li-redox flow batteries. Here we prepare a fast cubic perovskite Li+ conductor, Li3/8Sr7/16Ta3/4Hf1/4O3 (LSTH), by reducing the grain boundary resistance with spark plasma sintering. The influence of the sintering temperature and time on the relative density and the total Li+ conductivity of Li3/8Sr7/16Ta3/4Hf1/4O3 are investigated; the LSTH pellets sintered by SPS at 1250 degrees C for 10 min has a much higher density (96.5%), a higher Li+ conductivity (5.2 x 10(-4) S cm(-1)) at 25 degrees C and a lower activation energy (0.33 eV) than the Li3/8Sr7/16Ta3/4Hf1/4O3 pellet fired with conventional sintering. The symmetric Li/Li cell with a LSTH membrane, which is coated by a thin Li+-conducting solid polymer to avoid the chemical reduction of Li3/8Sr7/16Ta3/4Hf1/4O3 by a metallic lithium anode and to homogenize the current density at Li/electrolyte interface, shows a stable cycling at 0.3 mA cm(-2); the all-solid-state Li/LiFePO4 battery and the Li-S cell with Li3/8Sr7/16Ta3/4Hf1/4O3 membranes show a high coulombic efficiency and a good cycling life.
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